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Beilstein J. Org. Chem. 2016, 12, 2181–2188, doi:10.3762/bjoc.12.208
Graphical Abstract
Scheme 1: Distribution of products in the Diels–Alder reaction between cyclopentadiene and p-benzoquinone.
Figure 1: Conversion in the DAR catalysed by silica Beta zeolites and Aerosil.
Figure 2: Effect of Lewis and Brønsted acid sites in the conversion (a) and selectivity (b) of the DAR.
Figure 3: Effect of pore size in the conversion (a) and selectivity (b) of the DAR.
Figure 4: Comparison of conversion (a) and selectivity (b) of the DAR catalysed by Al-Beta zeolite and MCM-41....
Figure 5: Comparison of conversion (a) and selectivity (b) of the DAR catalysed extra-large pore 3D zeolites.
Figure 6: Effect of the Si/Al ratio in the conversion (a) and selectivity (b) of the DAR.
Figure 7: Effect of the reutilization of the catalysts in the conversion (a) and selectivity (b) of the DAR.